专利摘要:
1423376 Diphenylether derivatives ROHM & HAAS CO 13 March 1973 [14 March 1972 (2) 12 Feb 1973 (2)] 11954/73 Heading C2C The invention comprises compounds of the formula where X is hydrogen, halogen, trihalomethyl, C 1 -C 4 alkyl or cyano and (i) Y is halogen, trihalomethyl or, except where X is chlorine, hydrogen and Z is hydrogen or (ii) Y is hydrogen, halogen or trihalomethyl and Z is alkoxy, alkoxyalkoxy, hydroxyalkoxy, carboxyalkoxy, carbalkoxyalkoxy, halogen, alkylthio, alkyl, amino substituted with a dialkylcarbamoyl group, one or two alkyl groups, an alkylcarbonyl group or a carbalkoxy group, carboxy, carbalkoxy, carboxyalkyl or carbalkoxyalkyl. The compounds may be prepared by reacting a suitably substituted phenol or the potassium or sodium salt thereof with a halobenzene compound, or by introducing a substituent into a diphenyl ether. The compounds may be used as herbicides.
公开号:SU713520A3
申请号:SU731898369
申请日:1973-03-13
公开日:1980-01-30
发明作者:Отто Байер Хорст;Свитенбанк Колин;Янгминг.И Рой
申请人:Ром Энд Хаас Компани (Фирма);
IPC主号:
专利说明:

(.54) HERBICIDE COMPOSITION
The present invention will be applied to chemical agents to combat undesirable agent, which is associated with three plants.
Known heroul day composition based on derivatives D1i | The enlarged v (|) iipoB (|) 3.5 XiCeH-.O Sbn.;. From. | de X-C, Me. .Og group. n 2 or 4 2, 4, as well as such as 3-tr,; Hormetn.t-4-nitrodpheny.
The terbnnidic composition is known on the basis of and | waterstars ;; itrod} fennloto ether of the formula
SRt
ABOUT
about
ten
6
-Halper; a. - water gulp: h; :: R - metoke} t L n.iJi saturated n1 erd 1. However, the well-known herbicidal compositions have not been distributed; from pol1; from 1n the balance of broadleaf ::: stentiums and odnogolnykh in cereal govos; x. In order to enhance the herbicidal activity and the austerity of the action of the predisposition, a.ioreii. Trift Ormetnl, K1) L with chg1slom ATOMOv corner) to 4:; li c K1: Ogre Nla; ;: L; ged}: L1 tr1i |) tormaU5odorod. o; c; g: up11a. alko.sngrunsha to () childbirth. alknlpa. having up to 4 ltyols, uroi a .ioreif ;;. alinoggdta. Alkyltno: Alyuyuschaya to 4 carbon atoms, pn. carboxyl} 1 G1tuina, carl soil ..; -1m oydp to 4 ator in alkox; 1, fornon parts, ka; 1plna rDvnns. - meyunha up to 4 carbon atoms, carbalkoxy. per group having up to 6 carbon atoms, alkanoyloxy group having up to 4 carbon atoms, or carbamoyloxy group having up to 6 carbon atoms. as well as an additive selected from the group of solvent, emulsifier, dispersing agent (and, moreover, the weight of active ingredient ranges from 2 to 98% by weight). % Gerbptspdia kompotsptsp and its analysis are given in table. i; in tab. 2 shows the indicator of the gericidal activity of the proposed COMNOSITS1. t p about l and c and I
Tocr- i; i4ii; e
74 81 92 85
and I M-lCHaCFijOH
WITH
II AXLE.SOOLS Cl
I
and OCM, CO, C, H; Cl
MLI OSH (VIS) Cl Cl C
II
PI OCH (SNZ) CO, C, H5
and I NH.
and
Cl
OSISNIOS SI
n and l-I I-II
Cl och (SNZ) C SP Cl OOSACHaOSCH Cl Cl Cl Cl
axis (SNS) jays,
CCA T1S1-
M-ICOC.HS
HUSCO C1 Cl
SNS Cl
C1 Cl
about
/
shifts
Cl Cl
OCHoCHOHClljOti
11 II I and and OCI-bCl-l.SCIb Cl Cl
(SzN7-p) 2
OCFL.CH.SOjCH. Cl
(CH3) CH, CHOHOH Cl Cl Cl Cl
NHCOKHCIb
P
N4-ICOSC, M, i
II m
N (COSC, H5) i
with to
with I
A
Cl
SAL1 Cl Cl
Sozsmz
II and 11 11 n n
axis (CH3) with, CH3 Cl Cl; SNS (SNS)
COH (CH3) SOHMSN, Cl Cl
OCH (,) CO (CfI ::,) I (CaH5) CH2CH, Cl Cl
N (C, Il5) CO.HCH3
46.22 47.82 45.96 46.00 48.49 .60 4 7, 34, 34.35 49.78 49.8, 48.60 46.98
180-185
(0.04
M RT. Art.) I {4 - ia55
14.33 14.80 15.27 14.80 14.49 14, .12 14.26 14.12 14.76 14.00 14.71 14.08 14.90 13.93 16.95 17.19 18 48 48, 9
Continued table. 2
S, i
7-s
ABOUT
four
5D
note:
权利要求:
Claims (3)
[1]
Invention Formula
A herbicidal composition comprising an active principle based on 4-trifluoromethyl-4-nitro-prophenyl ether DERIVATIVES, as well as an additive selected from the group of a solvent, an emulsifier, a dispersant, about 1 hr; :. K) 1ts and with R telts, that. in order to enhance the 1-obicide of OI activity and selective; it contains 4-trifluoromethyl-4-n as it is irpidic 4-trifluoromethyl-4, itrodiphepyloxy ether; is a compound of the general form II where X is halogen, tr1 (|) tormetp, t} extrinsic alkyl with 15 carbon atoms from I to 4 or u; 1 ny 1pp; Y -) d. halogen) or 1tr; krto; 1metid; Z is hydrogen, oKCHrpyniia, alkoxprui-20 ia, and ieyui to ij atoms of carbon alkyl; ) aruyaa, imkm.cha up to 4 atoms .ia,;: halogen volume, a.migruguiaia, alky,: gigogroup. :: a. have .y 4 atoms of lchlerod, usiaHO | -ruiiia, carboxyl primer, carbalkok-25 si. gruii, having up to 4 atoms of yi.irode in the alkoxyl idio part, carboxyalkyl: that grunia, a termea to 4 carbon atoms, a carbalkoxyalkyl group, having up to () atoms of y-lyud, alkaioyloxngrun, 30 nomerio1 to 4 carbon atoms, go KajKiamonloxygrunna, | I., which has up to G carbon atoms, and the amount of weight content contained in the act;) Often, it ranges from 2 to 98 weight. / h 5 10 Priority on the basis of signs: 14.03.72 with Z - Bo; io | joa, a.iKOKciirpyiina, had () an atom of hlsrol. alkyl group :: a, having: t 4 atoms of carbon, atom 1al () 1mm1a, II alk1 ltiogr-ppa, having 4 .iTo.Moii yr.iejTOia. 12.02. 73 with X - ;; o; the fool, halogen, trifluorme:; 1Л. Hii.-iujnn alkyl by the number of carbon atoms,; and from 1 to -} or shagaiogroup; g; odo, chod, i i; ioixn и, 1и т) и (j) - - oxygrunia, а.миогиииа. cyano. | -ru11ia, carboxylia of the soil, carbalkoS11lüruiii, and it has up to 4 carbon atoms. Croda in the alcohol part, carboxa, IpyHiia lcilla, imemia and up to 4 carbon atoms. carbadkoxyadule group: 1ms (). about carbon atoms, alkanoylOKciirpyinia, .mile1O1a.cho 4 carbon atoms i.-ni carba (5) 1, k) 1 ui P1P1a, having: w b atolls at merod, Petochikiki kn (po }) The proceedings accepted by the z: nimaii irie examination: I. France Patent As 20651G3, cl. A 01 X (), C 07 C 79/00, oublenk. 1970.
[2]
2. Pate} Mr. Yaionnn L 13038, cl. 30 F 371, Mr. Pub. 1971
[3]
3. Patent Ang.cn L1 1014802, cd. L 5 EL 01 X 9/12,. 1963. 4. 11ATilJ.-l L 3454392, cl. 71-124. , 909.
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引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题

FR1602719A|1968-11-22|1971-01-18|Herbicidal diphenylether/pheny urea compos - ition |USRE32243E|1969-04-25|1986-09-09|Rhone-Poulenc Agrochimie|Esters of substituted phenoxybenzoic acids, compositions of the same and herbicidal use thereof|
USRE32216E|1969-04-25|1986-07-29|Rhone-Poulenc Agrochimie|Salts of substituted phenoxybenzoic acids, compositions of the same and herbicidal use thereof|
USRE32215E|1971-02-11|1986-07-22|Rhone-Poulenc Agrochimie|Substituted phenoxybenzoic acids compositions of the same and herbicidal use thereof|
JPS5436209B2|1972-10-24|1979-11-08|
EG11593A|1973-07-03|1980-07-31|Bayer Ag|Halogenated 4-trifluiromethyl-4-cyano-diphenyl-ethers process for their preparation and their use as herbicides|
JPS5068800U|1973-10-22|1975-06-19|
JPS5724761B2|1973-12-19|1982-05-26|
JPS50123824A|1974-03-15|1975-09-29|
JPS50132125A|1974-04-12|1975-10-20|
JPS5726561B2|1974-12-23|1982-06-05|
JPS5726642B2|1977-06-15|1982-06-05|
DE2938595A1|1979-09-24|1981-04-23|Celamerck Gmbh & Co Kg, 6507 Ingelheim|METHOD FOR PRODUCING DIPHENYL ETHERS|
DE2942930A1|1979-10-24|1981-05-27|Basf Ag, 6700 Ludwigshafen|SUBSTITUTED UREAS, THEIR PRODUCTION AND USE AS HERBICIDES|
DE3045805A1|1980-12-05|1982-07-08|Basf Ag, 6700 Ludwigshafen|DIPHENYL ETHER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS HERBICIDES|
DE3269621D1|1981-08-07|1986-04-10|Ciba Geigy Ag|Phenoxyphenyl-aminocarboxylic-acid derivatives, their preparation, compositions containing them and their use|
JP2801181B2|1983-01-10|1998-09-21|キヤノン株式会社|Sheet reversing device|
FR2549047B1|1983-07-12|1986-03-21|Rhone Poulenc Agrochimie|NOVEL HERBICIDES DERIVED FROM ARYLOXYBENZENES CARBONIMIDES|
EP0161529B1|1984-05-18|1989-07-12|Asahi Kasei Kogyo Kabushiki Kaisha|2-nitro-5-phenylacetic ester, thioester and amide, process for preparation therof, herbicidal composition, and method for destruction of undesirable weeds|
HU193466B|1984-11-12|1987-10-28|Budapesti Vegyimuevek|Fungicidal composition comprising 2-nitrobenzoic acid derivative as active substance|
JPS63157065U|1987-04-02|1988-10-14|
DE69902987T2|1998-12-23|2003-01-23|Dow Agrosciences Llc|Manufacture of diphenyl ethers|
法律状态:
优先权:
申请号 | 申请日 | 专利标题
US23465172A| true| 1972-03-14|1972-03-14|
US234656A|US3888932A|1972-03-14|1972-03-14|Herbicidal 4-trifluoromethyl-4-nitrodiphenyl ethers|
US05331719|US3928416A|1972-03-14|1973-02-12|Herbicidal 4-trifluoromethyl-4{40 nitrodiphenyl ethers|
US05/331,947|US4076741A|1972-03-14|1973-02-12|Herbicidal 4-trifluoromethyl-4-nitrodiphenyl ethers|
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